Toxicity profiles of Delta herbicides

California Delta herbicide control

Summer 2019

Imazamox, Penoxsulam and Agridex for floating aquatic vegetation control. Several varieties of Fluridone were used for control of submersed aquatic vegetation (SAV).

The SAV control program utilized Fluridone formulations such as: Sonar® PR (granular) and two pellet formulations, SonarOne ® and Sonar Q ® . The pellet and granular formulations provide different release profiles due to the characteristics of the inert clay ingredients.

As a first step, I researched the chemical and brand name, reviewed EPA and manufacturer documentation, the National Pesticide Information Center, along with the material safety data sheets (MSDS) to tabulate (Table 1) the basic information regarding the toxicity and hazards of each of these herbicides. Second, I reviewed previous years’ annual reports to summarize the quantities of herbicides applied across the Delta.

Table 1. Summary of herbicides used in control of surface and submersed aquatic vegetation by the California State Parks

Aquatic Invasive Plant Control Program in the California Delta.

®

CHEMICAL

BRAND NAME

EPA TOXICITY (LC50)

MSDS HAZARDS

Glyphosate

Round-Up

Fish acute toxicity

rainbow trout: >140 mg/L bluegill sunfish: >150 mg/L Aquatic invertebrate toxicity ( Daphnia magn a): >3 mg/L

Moderately Toxic

Caution: Causes moderate eye irritation. Low to moderately toxic to animal and

aquatic life.

2,4-D

Weedar 64

Fish acute toxicity

rainbow, cutthroat trout:

0.5-1.2 mg/L

Aquatic invertebrate toxicity

( Daphnia magna ): >5.2 mg/L High toxicity, chronic exposure 1

Early life stages fish most

susceptible

Keep out of reach of children. DANGER.

Corrosive. Causes irreversible eye damage. Harmful if swallowed. May be fatal if absorbed through the skin. Avoid breathing vapors or spray mist. Do not

get in eyes, on skin or on clothing.

Imazamox

Clearcast

Fish acute toxicity

rainbow trout: >122 mg/L bluegill sunfish: >119 mg/L Aquatic invertebrate toxicity ( Daphnia magna ): >122 mg/L

Caution: harmful if absorbed through skin. Harmful if inhaled. Keep out of

reach of children. Keep out of reach

of domestic animals. Avoid contact with the skin, eyes and clothing. Avoid

inhalation of mists/vapors.

Fluridone

Sonar (PR, One, Q)

Fish acute toxicity

rainbow trout: > 7.1 mg/L fathead minnow: > 41 mg/L Aquatic invertebrate toxicity ( Daphnia magna ): >97 ppb

Eye Irritation. Aquatic hazard (acute) –

Aquatic hazard (long-term)

Penoxsulam

Galleon

Fish acute toxicity

rainbow trout: >100 mg/L bluegill sunfish: >100 mg/L Aquatic invertebrate toxicity ( Daphnia magna ): >100 mg/L

Harmful if inhaled. Avoid breathing spray mist. Material is very highly toxic to aquatic organisms an acute basis in

most sensitive species.

Agridex 2

Fish acute toxicity

rainbow trout: >1000 mg/L bluegill sunfish: >1000 mg/L Aquatic invertebrate toxicity ( Daphnia magna ): >1000 mg/L

May be harmful if swallowed. May be harmful in contact with skin. Causes eye irritation. Causes mild skin

irritation. Harmful if inhaled.

1 Esters are moderately to slightly toxic, acids low to no toxicity. 2 Not an herbicide, but a surfactant used to improve effectiveness of foliar applications of herbicides.

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